Christopher Pike vs Marian Slingeneyer: who would win?

Marian Slingeneyer favored — Slight edge (~55%)

Christopher Pike · Star Trek · Normal

Tier
10-A, up to 8-C
Attack Potency
Below Average Human Level, up to Building Level
Speed
Athletic Human, up to Speed Of Light
Durability
Athlete Level

Marian Slingeneyer · Toaru Majutsu no Index · Base

Tier
9-C, up to HIGH 1-C
Attack Potency
Street Level, up to High Complex Multiverse Level
Speed
Average Human, up to Supersonic
Durability
Street Level

A heuristic estimate from normalized VS Battles Wiki stats: tier, attack potency, speed and durability.