Kihara Byouri vs Droideka: who would win?

Kihara Byouri favored — Slight edge (~55%)

Kihara Byouri · Toaru Majutsu no Index · Equ.DarkMatter implants

Tier
8-C
Attack Potency
Building Level
Speed
Supersonic
Durability
Street Level, up to Building Level

Droideka · Star Wars · Base

Tier
8-C
Attack Potency
Building Level
Speed
Average Human, up to Speed Of Light
Durability
Street Level, up to Building Level

A heuristic estimate from normalized VS Battles Wiki stats: tier, attack potency, speed and durability.