Jayna vs Bjorn: who would win?

Bjorn favored — Slight edge (~55%)

Jayna · DC · Base

Tier
9-C, up to 5-A
Attack Potency
Street Level, up to Large Planet Level
Speed
Massively Ftl+
Durability
Below Average Human Level, up to Large Planet Level

Bjorn · Vinland Saga · Base

Tier
9-C, up to 9-B
Attack Potency
Street Level, up to Wall Level
Speed
Unknown
Durability
Street Level, up to Wall Level

A heuristic estimate from normalized VS Battles Wiki stats: tier, attack potency, speed and durability.