James T. Kirk vs Hitomi Shizuki: who would win?

Hitomi Shizuki favored — Slight edge (~55%)

James T. Kirk · Star Trek · With the rigged Constellation

Tier
7-B
Attack Potency
City Level+
Speed
Sub-Relativistic+
Durability
City Level

Hitomi Shizuki · Puella Magi Verse · Nightmare

Tier
7-B
Attack Potency
City Level
Speed
Massively Hypersonic
Durability
Planet Level

A heuristic estimate from normalized VS Battles Wiki stats: tier, attack potency, speed and durability.